The cis fatty acids have lower melting points than the trans fatty acids or their saturated counterparts. Fat is energydense, meaning it is high in calories. Engineering microbial fatty acid metabolism for biofuels. Fatty acids are the main constituents of oils and fats, whose applications are overwhelming. Number of carbons from the carboxylic acid alpha end to the first carbon in the double bonds lets consider the example in the figure below. A fatty acid has at least one carboxyl group a carbon attached to two. A comprehensive evaluation of the melting points of fatty acids and. A common starting point for engineering microbial hosts is increasing the. A note on the meltingpoint of paraffins and fatty acids. As a result, the melting points are much lower for unsaturated fatty acids. Metabolic engineering strategies for fatty acidderived metabolites. At this point the chylomicrons can transport the triglycerides to tissues where they. A comprehensive evaluation of the melting points of fatty. Report of an expert consultation fao fats and fatty acids in human nutrition report of an expert consultation fao food and nutrition paper 91 issn 02544725 knowledge of the role of fatty acids in determining health and nutritional wellbeing has expanded dramatically in the past 15 years.
The tetrahedral bond angles on carbon results in a molecular geometry for saturated fatty acids that is relatively linear although with zigzags. The reason for this phenomenon can be found by a careful consideration of molecular geometries. In polyunsaturated fatty acids pufas the first double. The points for an odd number of carbon atoms lie on a separate but similar curve, exemplifying the wellknown alternation property. Major fatty acids fatty acids represent 3035% of total energy intake in many industrial countries and the most important dietary sources of fatty acids are vegetable oils, dairy products, meat products, grain and fatty. According to the rules in the who basic documents 58, whenever an expert or. If a similar diagram is made for the fatty acids, the points corresponding to an even number of carbon atoms lie on a curve of the same character as that found for paraffins. Most fatty acids have 12 to 20 carbons most chains have an evennumber of carbons synthesized from twocarbon units iupac nomenclature.
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